Communication: Creation of molecular vibrational motions via the rotation-vibration coupling
نویسندگان
چکیده
منابع مشابه
Non-adiabatic molecular Hamiltonian. Canonical transformation coupling electronic and vibrational motions
Ivan Hubač , Peter Babinec , Martin Polášek , Ján Urban , Pavel Mach b , Jozef Mášik b and Jerzy Leszczyński a Department of Chemistry, Jackson State University, 1400 Lynch Street, P.O. Box 17910, Jackson, MS 39217, USA Division of Chemical Physics, Faculty of Mathematics and Physics, Comenius University, Mlynská dolina F1, 842 15 Bratislava, Slovakia c Institute of Physics, Faculty of Science,...
متن کاملNonlinear coupling between rotation and internal vibration in simple molecular systems
A Hamiltonian is proposed to describe the coupling between vibration and rotation in a molecular system. The time behaviour of such a system exhibits both regular and irregular motion for different energies and different values of the coupling parameter. There is a dramatic manifestation of the transition between the two types of dynamics that define parametric regions of regular and irregular ...
متن کاملObservable frequency shifts via spin-rotation coupling
The phase perturbation arising from spin-rotation coupling is developed as a natural extension of the celebrated Sagnac effect. Experimental evidence in support of this phase shift, however, has yet to be realized due to the exceptional sensitivity required. We draw attention to the relevance of a series of experiments establishing that circularly polarized light, upon passing through a rotatin...
متن کاملEffect of molecular rotation on the vibration-vibration energy transfer in condensed media.
The purpose of the present communication has been to present the derivation of the vibrational relaxation rate constant for the case in which both phonons and the molecular rotation (three-dimensional) participate in the vibrational relaxation and to study the effect of molecular rotation on the vibration-vibration energy transfer in the condensed phase. The experimental results of vibration-vi...
متن کاملnew semigroup compactifications via the enveloping semigroups of associated flows
this thesis deals with the construction of some function algebras whose corresponding semigroup compactification are universal with respect to some properies of their enveloping semigroups. the special properties are of beigan a left zero, a left simple, a group, an inflation of the right zero, and an inflation of the rectangular band.
15 صفحه اولذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2015
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.4922309